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From Wuw Archive

All Star Mode is unlocked when you unlock every character. You fight every character and then go to a rest area. There you decide if you want to use one of the three healing items put out for you.

Your matches go like this.

• Match 1: Videlectrix Mascot.
• Match 2: Homestar's team.
• Match 3: Strong Bad's team.
• Match 4: Coach Z.
• Match 5: Poopsmith.
• Match 6: The TLA Team.
• Match 7: The Ert Plus Team.
• Match 8: Pter and Fang.
• Match 9: Slick's team.
• Match 10: 20X6 trio.
• Match 11: Zippy.
• Match 12: Bellstrom.
• Match 13: Homeschool.
• Match 14: Homsar.
• Match 15: Snake.
• Match 16: Foxxsuke's team.
• Match 17: Cyrus' team.
• Match 18: Lucas Aura.
• Extra Match (If you have all downloadable characters): Ryan, Good Deal Dan, Preshy and Rafferdry, Elyssa, and Mario.

When you beat All Star Mode, you get a Final Smash trophy.