Acids and Bases

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Contents

Acids

When dissolved in water, acids give off hydrogen ions (H+). This makes them proton donors.

  • An acid is monoprotic if one mole of it gives off one mole of hydrogen ions (HCl, for instance), and diprotic if one mole of it gives of two moles of hydrogen ions.
    • Acids can also be triprotic, quadroprotic etc. but you don't really need to know that.
  • strong acids dissolve completely in water, while weak acids only partially dissociate.
    • Therefore strong acids have more hydrogen ions in the water at a time, and react more quickly.
    • With a weak acid, when some of the hydrogen ions react and become something else, more of the acid dissociates to replenish the supply of H+ ions.
      • Therefore, a fixed amount (say one mole) of any monoprotic acid can be neutralized by a fixed amount of a base.
      • The same amount of a diprotic acid would require twice as much base to neutralize it.

Bases

When dissolved in water, acids give off hydroxide ions (OH-). This makes them proton receivers.

Acids and Bases to know

All numbers in the following chart should be in subscript format, but they're not. So too bad.

Type Name Formula
Strong acid Hydrochloric Acid HCl
Strong acid Sulphuric Acid H2SO4
Strong acid Nitric Acid HNO3
Weak acid Ethanoic Acid HNO3
Weak acid Carbonic Acid H2CO3
Strong base Sodium Hydroxide NaOH
Strong base Potassium Hydroxide KOH
Strong base Barium Hydroxide Ba(OH)2
Weak base Ammonia NH3
Weak base Aminoethane C2H5NH2

Measuring acidity

the pH Scale

Acidity is measured on a scale of pH (stands for the power of Hydrogen), from 0 to 14, with 0 being a really, really, freaking strong acid and 14 being a base potent enough to dissolve all of the lipids in your body real quick-like.

The pH of a solution is equal to the negative magnitude of the concentration of hydrogen ions in a solution.

    • If a solution has a concentration of 10^-2 M of hydrogen ions, it has a pH of 2.
  • Mathematically speaking, the pH is therefore equal to the negative log in base ten of the concentration of hydrogen ions.

pH Meters

pH meters measure the conductivity of a solution to determine its acidity.

Acidic solutions contain extra H+ ions, so they conduct electricity better. Conductivity increases as pH decreases

Indicators

Indicator solutions and indicator paper (paper soaked in indicator solution) are used to create a visual indication of the pH of a solution.

You have to know four of them:

Indicator Color in Acid Color in neutral solution Color in Base
phenolphthalein clear clear fuchsia
methyl orange red yellow yellow
litmus red purple blue

Universal indicator provides a range of colors, each corresponding to certain pH.

Here's an excellent graph of the three indicators and their colors.

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